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Structural and magnetic characterizations of the first manganese(iii) Schiff base complexes involving hexathiocyanidoplatinate(iv) bridges

✍ Scribed by Šilha, Tomáš; Nemec, Ivan; Herchel, Radovan; Trávníček, Zdeněk

Book ID
120435469
Publisher
Royal Society of Chemistry
Year
2013
Tongue
English
Weight
812 KB
Volume
15
Category
Article
ISSN
1466-8033

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## Abstract Four cyanido‐bridged Mn^III^–Cr^I^ heterodimetallic complexes have been synthesized by the reactions of Mn^III^ Schiff‐base complexes with the [Cr(CN)~5~(NO)]^3–^ building block. X‐ray diffraction analysis reveals that [Mn(5‐Cl‐salen)(H~2~O)~2~][Mn~2~(5‐Cl‐salen)~2~(H~2~O)~1.5~Cr(CN)~5~