## Abstract Four cyanido‐bridged Mn^III^–Cr^I^ heterodimetallic complexes have been synthesized by the reactions of Mn^III^ Schiff‐base complexes with the [Cr(CN)~5~(NO)]^3–^ building block. X‐ray diffraction analysis reveals that [Mn(5‐Cl‐salen)(H~2~O)~2~][Mn~2~(5‐Cl‐salen)~2~(H~2~O)~1.5~Cr(CN)~5~
✦ LIBER ✦
A one-dimensional azido-bridged manganese(III) complex with bidentate Schiff base: Crystal structure and magnetic properties
✍ Scribed by Wei Li; Zongwei Li; Licun Li; Daizheng Liao; Zonghui Jiang
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 436 KB
- Volume
- 180
- Category
- Article
- ISSN
- 0022-4596
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## Abstract The phenoxo‐bridged dinuclear Cu^II^ complex [Cu~2~L~2~(NCNCN)~2~] (1) and the dicyanamide‐bridged molecular rectangle [Cu~4~L~4~{μ~1,5~‐(NCNCN)~2~}]·(ClO~4~)~2~(H~2~O)~2~ (2) were synthesized using the tridentate reduced Schiff‐base ligand HL {2‐[(2‐dimethylamino‐ethylamino)methyl]phen