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Syntheses, structures and magnetic properties of the tricyanoethenolate adducts of quadridentate Schiff base manganese(III) complexes

✍ Scribed by Yoshiki Sato; Hitoshi Miyasaka; Naohide Matsumoto; Hisashi Ōkawa

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
613 KB
Volume
247
Category
Article
ISSN
0020-1693

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## Abstract Four cyanido‐bridged Mn^III^–Cr^I^ heterodimetallic complexes have been synthesized by the reactions of Mn^III^ Schiff‐base complexes with the [Cr(CN)~5~(NO)]^3–^ building block. X‐ray diffraction analysis reveals that [Mn(5‐Cl‐salen)(H~2~O)~2~][Mn~2~(5‐Cl‐salen)~2~(H~2~O)~1.5~Cr(CN)~5~