Structural and magnetic characterization of novel stoichiometric LnCaCrO4 oxides (Ln, rare earth)
✍ Scribed by Morales Sánchez, A.; Fernández, F.; Sáez Puche, R.; Fernández-Martín, F.
- Book ID
- 122789102
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 457 KB
- Volume
- 203
- Category
- Article
- ISSN
- 0925-8388
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Compounds of the series Ln 6 ReO 12 , Ln؍Ho, Er, Tm, Yb, and Lu, have been prepared by subsolidus reaction and are isotypic with Ln 6 MoO 12 , Ln 6 WO 12 , and Ln 6 UO 12 , crystallizing in space group R3 with Z3؍ for the R-centered setting. The magnetic moment per rhenium ion in Lu 6 ReO 12 is
A number of new quaternary rare-earth pyrochlores Ln 2 BSbO 7 are reported with Ln ¼ Pr, Nd, Eu, Gd or Dy, B ¼ Sc, Ga or In. These compositions extend the range of available rare-earth pyrochlores with diamagnetic B-site cations, especially for early lanthanides (Pr, Nd). Rietveld refinements and Mo