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Structures and magnetic properties of rare earth rhenium oxides Ln3ReO7 (Ln = Gd, Tb, and Dy)

✍ Scribed by Yukio Hinatsu; Makoto Wakeshima; Noriyoshi Kawabuchi; Nobuyuki Taira


Book ID
116597458
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
287 KB
Volume
374
Category
Article
ISSN
0925-8388

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Ternary lanthanide rhenium oxides Ln 3 ReO 7 (Ln ΒΌ Sm, Eu, Ho) were prepared and their structures were determined by X-ray diffraction measurements. They crystallize in an orthorhombic superstructure of cubic fluorite (space group Cmcm for Ln ΒΌ Sm, Eu; C222 1 for Ln ΒΌ Ho). The magnetic properties we

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Compounds of the series Ln 6 ReO 12 , Ln‫؍‬Ho, Er, Tm, Yb, and Lu, have been prepared by subsolidus reaction and are isotypic with Ln 6 MoO 12 , Ln 6 WO 12 , and Ln 6 UO 12 , crystallizing in space group R3 with Z‫3؍‬ for the R-centered setting. The magnetic moment per rhenium ion in Lu 6 ReO 12 is