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Structural and Energetic Effects in the Molecular Recognition of Acetylated Amino Acids by 18-Crown-6

✍ Scribed by Yu Chen, M. T. Rodgers

Book ID
118303483
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
517 KB
Volume
23
Category
Article
ISSN
1044-0305

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A practical synthesis of chiral amine precursors 3 and 4 and chiral diaza 18-crown-6 ethers 5, 6 and 7 starting from chiral amines are reported. The molecular recognition of these chiral crown ethers for amino acids potassium and sodium salts has been characterized by UV-vis. The selectivity order i