The interfacial reaction and phase formation as a function of the annealing temperature (600-10008C) and time were investigated on both titanium and nickel thin films evaporated on n-type 6H-SiC (0001) substrate. The study was carried out employing a combination of Rutherford backscattering spectrometry, X-ray diffraction, transmission electron microscopy and sheet resistance measurements. A correlation has been found between the annealing process and the electrical measurements on transmission line method (TLM) structures and Schottky diodes. In the case of titanium, the formation of different phases in the analysed temperature ranges significantly changes the electrical properties. In fact, while a double layer of TiC and Ti Si was formed 5 3 at 900 and 9508C, the ternary phase Ti SiC was observed only at 10008C. With this high temperature process 3 2 24 25 2 the specific contact resistance decreases from 10 to 6.7 3 10 Vcm . In the case of nickel silicide the only phase that has been observed between 600 and 9508C was the Ni Si. The carbon of the consumed silicon 2 carbide layer has been dissolved in the silicide film, during the reaction, forming carbon precipitates. The 25 2 specific contact resistance reaches the lowest value (3.6 3 10 Vcm ) after the highest temperature anneal. The Ni Si / SiC Schottky diodes show almost ideal characteristics (n 5 1.07) and a barrier height of | 1.3 eV. From 2 the electrical characterisation, a non-uniform Schottky barrier height seems to be formed.