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Straightforward Synthesis of Thiodisaccharides by Ring-Opening of Sugar Epoxides

✍ Scribed by Manzano, Verónica E.; Uhrig, María Laura; Varela, Oscar


Book ID
121874720
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
362 KB
Volume
73
Category
Article
ISSN
0022-3263

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## Abstract A variety of hydroxy epoxides have been obtained from well defined hydroxy‐alkenyl derivatives. Their subsequent intramolecular ring‐opening allowed unprecedented classes of spiro‐lactams to be obtained. The effect of the epoxide stereochemistry and of the reaction temperature on the re