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Stoichiometry, kinetics, and mechanisms of the chromium(VI) oxidation of L-cysteine at neutral pH

✍ Scribed by Kwong, Daniel W. J.; Pennington, David E.


Book ID
127081344
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
658 KB
Volume
23
Category
Article
ISSN
0020-1669

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The permanganate oxidation of L-valine has been studied by visible spectrophotometry in neutral aqueous solutions. Under these conditions, both the zwitterionic and anionic forms of the amino acid are oxidized, the reaction being autocatalyzed by soluble colloidal manganese dioxide. Kinetic data for