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Micellar effect on the kinetics and mechanism of chromium(VI) oxidation of organic substrates

โœ Scribed by Asim K. Das

Book ID
108082492
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
276 KB
Volume
248
Category
Article
ISSN
0010-8545

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The kinetics of oxidation of N,N-dimethylformamide by chromium(VI) has been studied spectrophotometrically in aqueous perchloric acid media at 20ะŠC. The rate showed a first-order dependence on both [Cr(VI)] and [DMF], and increased markedly with increasing [H ฯฉ ]. The order with respect to [HClO 4 ]