Kinetics and mechanism of the technetium(VII) oxidation of L-cysteine
β Scribed by F. Grases; J. Palou; E. Amat
- Book ID
- 105016314
- Publisher
- Springer
- Year
- 1986
- Tongue
- English
- Weight
- 300 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0340-4285
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The pertechnetate ion oxidizes ascorbic acid in strong acid medium to form red species. A reaction mechanism has been developed which correctly predicts all the experimental facts. The results obtained support the postulate according to which the red species corresponds to a complex formed between T
## Abstract The principal reactants interact in a molar ratio of 2:1 forming dihydroindophenol and the corresponding disulfide. The order of reaction is unity with respect to each reactant, namely, __N__βacetyl Lβcysteine and indophenol. The rate shows an inverse linear relation with hydroxyl ions.