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Steroids ccxciii. The methylenation of unsaturated ketones. Part i. addition of difluoromethylene to enones.

โœ Scribed by C. Beard; N.H. Dyson; J.H. Fried


Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
217 KB
Volume
7
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


We would like to report the first examples of the addition of difluoromethylene to the conjugated double bond of an enone system to yield gem-difluorocyclopropyl ketones. The


๐Ÿ“œ SIMILAR VOLUMES


AM1 calculations of parts of the enthalp
โœ S. El-Taher; M. H. Elnagdi ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 219 KB ๐Ÿ‘ 1 views

The nucleophilic additions of active methylene nitriles (MNs), R 1 R 2 CH โ€ซืžโ€ฌ , where R 1 โ€ซืกโ€ฌCN and R 2 โ€ซืกโ€ฌCN, and CSNH 2 , to acetaldehyde and to the resultant โฃ,b-unsaturated nitriles have been studied theoretically by the AM1 semiempirical MO method. The additions of MNs anions to acetaldehyde ar