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ChemInform Abstract: Phosphine Effects in the Copper(I) Hydride-Catalyzed Hydrogenation of Ketones and Regioselective 1,2-Reduction of α,β-Unsaturated Ketones and Aldehydes. Hydrogenation of Decalin and Steroidal Ketones and Enones.

✍ Scribed by Jian-Xin Chen; John F. Daeuble; Jeffrey M. Stryker

Publisher: John Wiley and Sons
Year: 2001
Weight: 39 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200114056

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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A New Halogen-Exchange Reaction Between Sn-F and Li-X: Selective 1,2-and 1,4-Reductions of α,β-Unsaturated Ketones and Effects of Halogen Substituents on the Regioselectivity of Organotin Hydrides. -In dependence of the additive a highly regioselective reduction is obtained under optimized condition