We would like to report the first examples of the addition of difluoromethylene to the conjugated double bond of an enone system to yield gem-difluorocyclopropyl ketones. The
Steroids CCCII. The methylenation of unsaturated ketones part IV. The 1:4-addition of difluoromethylene to an enone
β Scribed by P. Hodge; J.A. Edwards; J.H. Fried
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- French
- Weight
- 182 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The nucleophilic additions of active methylene nitriles (MNs), R 1 R 2 CH β«Χβ¬ , where R 1 β«Χ‘β¬CN and R 2 β«Χ‘β¬CN, and CSNH 2 , to acetaldehyde and to the resultant β£,b-unsaturated nitriles have been studied theoretically by the AM1 semiempirical MO method. The additions of MNs anions to acetaldehyde ar
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