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Steric effects on activation energy for the electrochemical oxidation of organocobaloximes

✍ Scribed by G Costa; A Puxeddu; C Tavagnacco; R Dreos-Garlatti


Book ID
108324283
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
816 KB
Volume
89
Category
Article
ISSN
0020-1693

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## Abstract Equilibrium constants for oxidations of cyclanols by cyclohexanone in benzene have been determined in the presence of aluminium isopropoxide. The free energies of the equilibrium (Ξ”__G__~ox~) are correlated with equilibrium constants for dissociation of cyanohydrins, rate constants for