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Steric and pH effects on the rate of Dakin oxidation of acylphenols

✍ Scribed by Hocking, M. B.; Bhandari, K.; Shell, B.; Smyth, T. A.

Book ID
111913599
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
920 KB
Volume
47
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

Steric Effects on Reaction Rates. Rate a
Steric Effects on Reaction Rates. Rate and equilibrium constants for oxidation of cyclanols
✍ Paul MΓΌller; Jacky Blanc πŸ“‚ Article πŸ“… 1980 πŸ› John Wiley and Sons 🌐 German βš– 393 KB πŸ‘ 2 views

## Abstract Equilibrium constants for oxidations of cyclanols by cyclohexanone in benzene have been determined in the presence of aluminium isopropoxide. The free energies of the equilibrium (Ξ”__G__~ox~) are correlated with equilibrium constants for dissociation of cyanohydrins, rate constants for