## Abstract Equilibrium constants for oxidations of cyclanols by cyclohexanone in benzene have been determined in the presence of aluminium isopropoxide. The free energies of the equilibrium (Δ__G__~ox~) are correlated with equilibrium constants for dissociation of cyanohydrins, rate constants for
Steric effects on reaction rates II: Rate and equilibrium constants for oxidation of bicyclic alcohols
✍ Scribed by Paul Müller; Jacky Blanc
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 215 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The rates of oxidation with chromic acid of 15 bi‐ and polycyclic secondary alcohols have been measured and correlated with strain changes calculated by the MM1‐program between the alcohols and the corresponding ketones. A correlation of the same quality is obtained upon representation
The pressure effect on the forward and backward rate constants and equilibrium constants of the Diels-Alder reaction of 9-chloroanthracene with tetracyanoethylene has been investigated in 1,2-dichloroethane up to 1000 kgcm -2 at 298.15 K. The reaction volume obtained from the pressure effect on equi