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Stereospecific Synthesis of Intermediates for 11-Aza-11-deoxy and 11-Azaprostaglandin Analogues from L-Arabinose


Book ID
120302328
Publisher
Taylor and Francis Group
Year
1992
Tongue
English
Weight
600 KB
Volume
22
Category
Article
ISSN
0039-7911

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✍ Jean-Claude Barrière; Angèle Chiaroni; Jeanine Cléophax; Stephan D. Géro; Claude 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 German ⚖ 242 KB

## Abstract We describe a flexible, stereocontrolled synthesis of enantiomerically pure substituted cyclopentenes and cyclopentanes ‐ including 11α‐hydroxy‐13‐oxaprostanoic acid **20** ‐ (−)‐quinic acid __via__ an acyclic precursor **6** by an intramolecular aldolisation‐dehydration reaction.