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Stereospecific Synthesis of 1,2-Dioxolanes by Alkoxy Radical β-Fragmentation of Steroidal Cyclic Peroxyhemiacetals

✍ Scribed by Boto, Alicia; Hernández, Rosendo; Velázquez, Silvia M.; Suárez, Ernesto; Prangé, Thierry


Book ID
124055098
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
127 KB
Volume
63
Category
Article
ISSN
0022-3263

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ChemInform Abstract: β-Fragmentation of
✍ M. Adinolfi; G. Barone; A. Iadonisi 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

β-Fragmentation of Anomeric Alkoxy Radicals from 1,3,4,5-Tetra-O-benzylhex-2-ulopyranoses: A Simple Synthesis of New Aldehydo Tetrose Building Blocks. -1,3,4,5-tetra-O-benzylhex-2-ulopyranoses (I) can be easily cleaved to the new aldehyde tetroses (II) via a mechanism involving Suarez fragmentation