✦ LIBER ✦
ChemInform Abstract: β-Fragmentation of Anomeric Alkoxy Radicals from 1,3,4,5-Tetra-O-benzylhex-2-ulopyranoses: A Simple Synthesis of New Aldehydo Tetrose Building Blocks.
✍ Scribed by M. Adinolfi; G. Barone; A. Iadonisi
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
β-Fragmentation of Anomeric Alkoxy Radicals from 1,3,4,5-Tetra-O-benzylhex-2-ulopyranoses: A Simple Synthesis of New Aldehydo Tetrose Building Blocks.
-1,3,4,5-tetra-O-benzylhex-2-ulopyranoses (I) can be easily cleaved to the new aldehyde tetroses (II) via a mechanism involving Suarez fragmentation of an anomeric alkoxy radical. -(ADINOLFI,