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ChemInform Abstract: Stereospecific Synthesis of 1,2-Dioxolanes by Alkoxy Radical β-Fragmentation of Steroidal Cyclic Peroxyhemiacetals.

✍ Scribed by A. BOTO; R. HERNANDEZ; S. M. VELAZQUEZ; E. SUAREZ; T. PRANGE


Publisher
John Wiley and Sons
Year
2010
Weight
43 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: β-Fragmentation of
✍ M. Adinolfi; G. Barone; A. Iadonisi 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB

β-Fragmentation of Anomeric Alkoxy Radicals from 1,3,4,5-Tetra-O-benzylhex-2-ulopyranoses: A Simple Synthesis of New Aldehydo Tetrose Building Blocks. -1,3,4,5-tetra-O-benzylhex-2-ulopyranoses (I) can be easily cleaved to the new aldehyde tetroses (II) via a mechanism involving Suarez fragmentation