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Stereospecific rhenium catalyzed desulfurization of thiiranes

โœ Scribed by Jacob, Josemon; Espenson, James H.


Book ID
121363180
Publisher
Royal Society of Chemistry
Year
1999
Tongue
English
Weight
148 KB
Volume
11
Category
Article
ISSN
1359-7345

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The first metal catalyzed route for the desulfurization of thiiranes (episulfidesl is described. In 1983, one of us2 reported the regiospecific, rhodium(I) catalyzed insertion of carbon monoxide into an aziridine to give a 8-lactam. This metal catalyzed carbonylation-ring P

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