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Desulfurization of Thiiranes with Iodine

โœ Scribed by Helmkamp, G. K.; Pettitt, D. J.


Book ID
127368489
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
236 KB
Volume
27
Category
Article
ISSN
0022-3263

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Stereospecific rhodium(I) catalyzed desu
โœ Serge Calet; Howard Alper ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 186 KB

The first metal catalyzed route for the desulfurization of thiiranes (episulfidesl is described. In 1983, one of us2 reported the regiospecific, rhodium(I) catalyzed insertion of carbon monoxide into an aziridine to give a 8-lactam. This metal catalyzed carbonylation-ring P