Stereospecific rhodium(I) catalyzed desulfurization of thiiranes

✍ Scribed by Serge Calet; Howard Alper

• Publisher: Elsevier Science
• Year: 1986
• Tongue: French
• Weight: 186 KB
• Volume: 27
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)84852-2

✦ Synopsis

The first metal catalyzed route for the desulfurization of thiiranes (episulfidesl is described.

In 1983, one of us2 reported the regiospecific, rhodium(I) catalyzed insertion of carbon monoxide into an aziridine to give a 8-lactam.

This metal catalyzed carbonylation-ring P