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Rhodium (I) catalyzed valence isomerization of quadricyclanes

โœ Scribed by H. Hogeveen; B.J. Nusse


Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
184 KB
Volume
14
Category
Article
ISSN
0040-4039

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Mechanistic differences between the Rh(I
โœ H. Hogeveen; B.J. Nusse ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 209 KB

We have reported' that treatment of the quadricyclene I with catalytic Ph2(norbornadiene)2C12 or Bh2(CO) Cl in CHCl 4 2 3 gives the norbornadiene II as the product. However, Nelson, Gillespie and Hinzhave shown that treatment of I with