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Stereospecific reactions of optically pure menthyl methylphosphinate

✍ Scribed by Benschop, H. P.; Platenburg, D. H. J. M.; Meppelder, F. H.; Boter, H. L.


Book ID
120553660
Publisher
Royal Society of Chemistry
Year
1970
Weight
175 KB
Volume
1
Category
Article
ISSN
0577-6171

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Stereospecific reduction of diastereomer
✍ Yasuhiro Koide; Atsushi Sakamoto; Tsuneo Imamoto πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 French βš– 140 KB

Diastereomerically pure menthyl phosphinates are stereospecifically reduced by lithium 4,4'-di-fertbutylbiphenylide. Subsequent treatment with alkyl halides affords phosphine oxides with high optical purity.