✦ LIBER ✦
Stereospecific reduction of diastereomerically pure menthyl phosphinates: a new route to optically active phosphine oxides
✍ Scribed by Yasuhiro Koide; Atsushi Sakamoto; Tsuneo Imamoto
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- French
- Weight
- 140 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Diastereomerically pure menthyl phosphinates are stereospecifically reduced by lithium 4,4'-di-fertbutylbiphenylide.
Subsequent treatment with alkyl halides affords phosphine oxides with high optical purity.