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Stereospecific Synthesis of Optically Pure Quinic Acid and Shikimic Acid from D-Arabinose

✍ Scribed by Prof. Dr. Hans Jürgen Bestmann; Dr. Hans August Heid


Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
231 KB
Volume
10
Category
Article
ISSN
0044-8249

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## Abstract The chemical synthesis of 99% enriched D(‐)‐[1,7‐^13^C~2~]shikimic acid from [1,2‐^13^C~2~]acetate in 25% overall yield is described. A two‐carbon phosphonate synthon was prepared from [1,2‐^13^C~2~]acetate and used in the shikimate synthesis of Fleet and coworkers.