Stereospecific formation of 1,2-epoxypropane, 1,2-epoxybutane and 1-chloro-2,3-epoxypropane by alkene-utilizing bacteria
✍ Scribed by A.Q.H. Habets-Crützen; S.J.N. Carlier; J.A.M. de Bont; D. Wistuba; V. Schurig; S. Hartmans; J. Tramper
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 497 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0141-0229
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## Synopsis l-Chloro-2,3-epoxypropane (CEP) reacts with excess of amines giving linear, thermally stable amino polymers, useful as dyeability modifiers for synthetic fibers. The polycondensation of 1- chloro-2,3-epoxypropane with amines is described, and preparations of such polymers are given: th
A novel stereospecific isomerization reaction of 3-substituted-3-bromo-1,2-epoxypropane derivatives into 1-substituted-3-bromo-1,2-epoxypropane derivatives is described. The choice of the solvent crucially influences the isomerization. The tendency of this isomerization could be predicted by compari