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Stereospecific cycloreversion of an azoalkane cation radical: the role of the 1,4-biradical

โœ Scribed by Zona, Thomas A.; Goodman, Joshua L.


Book ID
126253426
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
205 KB
Volume
115
Category
Article
ISSN
0002-7863

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The radical cation of hexafluoro-1,3-but
โœ M. Shiotani; H. Kawazoe; J. Sohma ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 401 KB

Two distinct radical cations have been observed by ESR in a-y-irradiated solid solution of hexafluoro-1,3-butadienc in freon. INDO calculations of ESR parameters showed that they were the cisoid CC& and tiansoid (Gh) forms of the planar hesafluoroburadicne radical cation. The unpaired electron occup