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ESR evidence for the stereospecific formation of the chair cyclohexane-1,4-diyl radical cation from both bicyclo[2.2.0]hexane and 1,5-hexadiene

โœ Scribed by Williams, Ffrancon; Guo, Qing Xiang; Bebout, Deborah C.; Carpenter, Barry K.


Book ID
120023271
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
265 KB
Volume
111
Category
Article
ISSN
0002-7863

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The radical cation of 1,4-dihydropentale
โœ Thomas Bally; Leo Truttmann; Sheng Dai; Jih Tzong Wang; Ffrancon Williams ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 761 KB

In contrast to recent claims by Rhodes and Glidewell, comparison of both ESR and electronic absorption spectra shows that the photoproduct of the recently characterized radical cation of bicyclo[ 3.3.0]octa-2,6-diene-4,8-diyl is identical to the 1,4dihydropentalene radical cation, i.e. a linear conj