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Stereospecific construction of three contiguous quaternary carbon atoms. Synthesis of (±)-3-methoxythaps-8-ene

✍ Scribed by A. Srikrishna; D.B. Ramachary


Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
89 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis


Synthesis of (±)-3-methoxythapsene via stereospecific construction of three contiguous quaternary carbon atoms, employing a combination of a Claisen rearrangement and an intramolecular diazoketone cyclopropanation as key reactions, is described.


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