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Stereospecific construction of stereogenic vicinal quaternary carbon atoms. Enantiospecific synthesis of (+)-valerane

โœ Scribed by Adusumilli Srikrishna; Ranganathan Viswajanani


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
138 KB
Volume
37
Category
Article
ISSN
0040-4039

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Stereospecific construction of three con
โœ A. Srikrishna; D.B. Ramachary ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 89 KB

Synthesis of (ยฑ)-3-methoxythapsene via stereospecific construction of three contiguous quaternary carbon atoms, employing a combination of a Claisen rearrangement and an intramolecular diazoketone cyclopropanation as key reactions, is described.