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Stereospecific catalysis in the polymerization of dienes under the influence ofπ-allyl complexes of transition metals

✍ Scribed by B. A. Dolgoplosk; E. I. Tinyakova


Book ID
112421933
Publisher
Springer
Year
1970
Tongue
English
Weight
1021 KB
Volume
19
Category
Article
ISSN
1573-9171

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Some aspects of copolymerization of dien
✍ B.A. Dolgoplosk; S.I. Beilin; Yu.V. Korshak; G.M. Chernenko; L.M. Vardanyan; M.P 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 671 KB

Abstract~-Allyl complexes of nickel induce stereospecific homopolymerization of cyclohexadiene-1,3 and 2,3-dimethylbutadiene with the formation of crystalline polymers. These polymers consist of 1,4-monomer units in cis-configuration for polycyclohexadiene and in trans-configuration for poly-2,3-dim