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Stereoselective α-amidoalkylation reactions of phenylglycinol-derived bicyclic lactams

✍ Scribed by Mercedes Amat; Carmen Escolano; Núria Llor; Marta Huguet; Maria Pérez; Joan Bosch

Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
173 KB
Volume
14
Category
Article
ISSN
0957-4166

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Diels–Alder reactions of phenylglycinol-
Diels–Alder reactions of phenylglycinol-derived bicyclic lactams. Enantiodivergent synthesis of cis-hydroisoquinolines
✍ Núria Casamitjana; Mercedes Amat; Núria Llor; Marçal Carreras; Xavier Pujol; M. 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 302 KB

The diastereomeric phenylglycinol-derived unsaturated d-lactams trans-3 and cis-3 react with dienes with exo facial diastereoselectivity to give the corresponding tricyclic adducts, which were ultimately converted to enantiomeric cis-hydroisoquinolines.