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Enantioselective Formal Synthesis of Uleine Alkaloids from Phenylglycinol-Derived Bicyclic Lactams.

✍ Scribed by Mercedes Amat; Maria Perez; Nuria Llor; Marisa Martinelli; Elies Molins; Joan Bosch

Publisher
John Wiley and Sons
Year
2004
Weight
32 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

A Simple Stereoselective Synthesis of En
A Simple Stereoselective Synthesis of Enantiopure 2-Substituted Pyrrolidines and Piperidines from Chiral (R)-Phenylglycinol-Derived Bicyclic 1,3-Oxazolidines
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Chiral, nonracemic 2-substituted pyrrolidines and piperidines were prepared in high ee and moderate to good chemical yields in three steps from (R)-phenylglycinol and Ξ³-or Ξ΄chloroketones. The key step of the synthesis was the stereo-