Stereoselective Transformation of Easily Available (2Z,4E)-2,4-Alkadien-1-ols into (E)-3-Alkene-1,2,5-triol Derivatives.
✍ Scribed by Shinya Yoshida; Moriteru Asano; Yuichi Kobayashi
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 33 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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## Abstract An efficient method to obtain 3E‐alkene‐1,2,5‐triol derivatives with 1,2‐anti stereoselectivity from the corresponding 2Z,4E‐alkadienyl alcohols, which are synthesized by Ni‐catalyzed coupling reaction between lithium 1E‐alkenyl borates and 1‐halo‐1Z‐alken‐3‐ols such as (IX), is describ
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