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ChemInform Abstract: Synthesis of the 1,2-anti Type of 3E-Alkene-1,2,5-triol Derivatives.

✍ Scribed by Yuichi Kobayashi; Akira Takeuchi; Hatsuhiko Hattori

Publisher: John Wiley and Sons
Year: 2010
Weight: 83 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201034056

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✦ Synopsis

Abstract

An efficient method to obtain 3E‐alkene‐1,2,5‐triol derivatives with 1,2‐anti stereoselectivity from the corresponding 2Z,4E‐alkadienyl alcohols, which are synthesized by Ni‐catalyzed coupling reaction between lithium 1E‐alkenyl borates and 1‐halo‐1Z‐alken‐3‐ols such as (IX), is described.

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