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Stereoselective Total Synthesis of Xestodecalactone C

✍ Scribed by Karuturi Rajesh; Vangaru Suresh; Jondoss Jon Paul Selvam; Chitturi Bhujanga Rao; Yenamandra Venkateswarlu

Book ID
102260261
Publisher
John Wiley and Sons
Year
2009
Tongue
German
Weight
168 KB
Volume
92
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

A simple and highly efficient stereoselective total synthesis of xestodecalactone C (IIb), a polyketide natural product, was achieved (Scheme 2). The synthesis involved Keck's asymmetric allylation, a iodine‐induced electrophilic cyclization, and an intramolecular Friedel–Crafts acylation as key steps.

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