✦ LIBER ✦

The stereoselective total synthesis of xestodecalactone C and epi-sporostatin via the Prins cyclisation

✍ Scribed by J.S. Yadav; N. Thrimurtulu; K. Uma Gayathri; B.V. Subba Reddy; A.R. Prasad

Book ID: 104095776
Publisher: Elsevier Science
Year: 2008
Tongue: French
Weight: 166 KB
Volume: 49
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2008.08.096

No coin nor oath required. For personal study only.

✦ Synopsis

Syntheses of xestodecalactone C and epi-sporostatin are described utilising Prins cyclisations, Mitsunobu reaction and intramolecular Friedel-Crafts acylation. The approach is convergent and highly stereoselective.

📜 SIMILAR VOLUMES

The first stereoselective and the total

The first stereoselective and the total synthesis of Leiocarpin C and total synthesis of (+)-Goniodiol

✍ J.S. Yadav; K. Premalatha; S.J. Harshavardhan; B.V. Subba Reddy 📂 Article 📅 2008 🏛 Elsevier Science 🌐 French ⚖ 151 KB

Stereoselective Synthesis of anti-1,3-Di

Stereoselective Synthesis of anti-1,3-Diol Units via Prins Cyclization: Application to the Synthesis of (-)-Sedamine.

✍ J. S. Yadav; M. Sridhar Reddy; P. Purushothama Rao; A. R. Prasad 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 25 KB 👁 2 views

Studies Toward the Total Synthesis of Ir

Studies Toward the Total Synthesis of Irumamycin: Stereoselective Preparation of the C(15)—C(27) Segment via Two-Directional Chain Synthesis.

✍ Tomoyasu Hirose; Toshiaki Sunazuka; Daisuke Yamamoto; Mutsumi Mouri; Yoshiaki Ha 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 15 KB 👁 1 views

The Stereoselective Total Synthesis of (

The Stereoselective Total Synthesis of (6S)-5,6-Dihydro-6-[(2R)-2-hydroxy-6-phenylhexyl]-2H-pyran-2-one via Prins Cyclization

✍ Jhillu Singh Yadav; Dandekar Chandrakanth; Yerragorla Gopala Rao; Kontham Ravind 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 German ⚖ 180 KB

## Abstract The stereoselective total synthesis of an antiproliferative and antifungal __α__‐pyrone natural product (6__S__)‐5,6‐dihydro‐6‐[(2__R__)‐2‐hydroxy‐6‐phenylhexyl]‐2__H__‐pyran‐2‐one is described. The key steps involved are the __Prins__ cyclization, __Mitsunobu__ reaction, and ring‐closi

Application of the AAA Reaction to the S

Application of the AAA Reaction to the Synthesis of the Furanoside of C-2-epi-Hygromycin A: A Total Synthesis of C-2-epi-Hygromycin A

✍ Barry M. Trost; Joseph Dudash; Jr.; Olivier Dirat 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 210 KB 👁 2 views

A strategy for stereocontrolled syntheses of furanoside type of natural products is developed for a glycosyl aryl ether. This strategy resolves the issue of low diastereoselectivity typical of normal glycosidation methods for furanosides. All the stereochemistry ultimately derives from a desymmetriz

ChemInform Abstract: An Efficient Approa

ChemInform Abstract: An Efficient Approach to the Stereoselective Synthesis of 2,6-Disubstituted Dihydropyrans via Stannyl-Prins Cyclization.

✍ Magdalena Dziedzic; Bartlomiej Furman 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 43 KB 👁 2 views