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Studies Toward the Total Synthesis of Irumamycin: Stereoselective Preparation of the C(15)—C(27) Segment via Two-Directional Chain Synthesis.

✍ Scribed by Tomoyasu Hirose; Toshiaki Sunazuka; Daisuke Yamamoto; Mutsumi Mouri; Yoshiaki Hagiwara; Takanori Matsumaru; Eisuke Kaji; Satoshi Imura


Publisher
John Wiley and Sons
Year
2007
Weight
15 KB
Volume
38
Category
Article
ISSN
0931-7597

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Studies Directed Toward the Total Synthesis of Scytophycin C: Synthesis of the C 1 -C 18 Fragment of Scytophycin C. -The synthesis of the C-1 to C-18 fragment (X) is based on a highly stereoselective carbon Ferrier-type rearrangement reaction of deoxyglucal (I) and the silyl enol ether (II). -(GRIEC