Stereoselective total synthesis of ieodomycin C
✍ Scribed by Tungen, Jørn E.; Aursnes, Marius; Hansen, Trond Vidar
- Book ID
- 121795644
- Publisher
- Elsevier Science
- Year
- 2014
- Tongue
- French
- Weight
- 364 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract A simple and highly efficient stereoselective total synthesis of xestodecalactone C (**IIb**), a polyketide natural product, was achieved (__Scheme 2__). The synthesis involved __Keck__'s asymmetric allylation, a iodine‐induced electrophilic cyclization, and an intramolecular __Friedel_
## Abstract A convergent and efficient total synthesis of stagonolide C (**1**), a phytotoxic metabolite, was achieved (__Schemes 2__ and __3__) The synthesis exploited the high configuration control in the __Prins__ cyclization along with alkene rearrangement and ring‐closing metathesis as key ste