Stereoselective Total Synthesis of Passifloricin A
β Scribed by Reddy, Cheruku Ravindra; Veeranjaneyulu, Boyapati; Nagendra, Siddavatam; Das, Biswanath
- Book ID
- 120013792
- Publisher
- John Wiley and Sons
- Year
- 2013
- Tongue
- German
- Weight
- 190 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0018-019X
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π SIMILAR VOLUMES
A new synthesis of (-)-rishitin (1) is reported, starting with chiral pool molecules. The crucial step is a stereo,selective vinyl radical eyelization, which gives a 10:1 ratio of 21 to 22.
A facile stereoselective total synthesis of secondary metabolite (+)-polyrhacitide A is described. Stereoselective aldol reaction, Horner-Wardsworth-Emmons reaction, Evans acetal intramolecular oxa-Michael reaction and diastereoselective syn reduction reaction are the key steps involved in the targe