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Stereoselective Synthesis of the Antiprotozoal Lactone Passifloricin A and Seven Isomers Thereof

✍ Scribed by Murga, Juan; García-Fortanet, Jorge; Carda, Miguel; Marco, J. Alberto

Book ID
120199111
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
143 KB
Volume
69
Category
Article
ISSN
0022-3263

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✍ Dominic L. Laventine; Paul M. Cullis; Marcos D. García; Paul R. Jenkins 📂 Article 📅 2009 🏛 Elsevier Science 🌐 French ⚖ 622 KB

We present here the application of Grubbs' 2nd generation catalyst for the ring-closing metathesis of electron-deficient a,b-unsaturated amides and esters leading to the synthesis of enantiopure azepinone and oxepinone derivatives on a carbohydrate glycoside scaffold. The relative stereochemistries