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Stereoselective total synthesis of (+)-polyrhacitide A

✍ Scribed by J.S. Yadav; G. Rajendar; B. Ganganna; P. Srihari

Publisher: Elsevier Science
Year: 2010
Tongue: French
Weight: 313 KB
Volume: 51
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2010.02.070

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✦ Synopsis

A facile stereoselective total synthesis of secondary metabolite (+)-polyrhacitide A is described. Stereoselective aldol reaction, Horner-Wardsworth-Emmons reaction, Evans acetal intramolecular oxa-Michael reaction and diastereoselective syn reduction reaction are the key steps involved in the target synthesis.

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