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Stereoselective total synthesis of cytotoxic sporiolide A

✍ Scribed by D. Kumar Reddy; K. Rajesh; V. Shekhar; D. Chanti Babu; Y. Venkateswarlu

Book ID: 104098198
Publisher: Elsevier Science
Year: 2010
Tongue: French
Weight: 241 KB
Volume: 51
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2010.08.014

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✦ Synopsis

A simple and highly efficient stereoselective total synthesis of cytotoxic agent sporiolide A has been achieved starting from D-mannitol; the strategy of synthesis utilizes stereoselective zinc-mediated allylation, aldol coupling and ring-closing metathesis as key steps.

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