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The First Total Synthesis of Sporiolide B.

✍ Scribed by Qi Chen; Yuguo Du

Publisher
John Wiley and Sons
Year
2007
Weight
12 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

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## Abstract The first total synthesis of the cytotoxic oxylipin Topsentolide B~3~ has been accomplished in 15 steps with an overall yield of 24 %. Starting with readily available __cis__‐butene diol as a synthon, the synthesis involved Marouka allylation and Sharpless hydroxylation for the construc