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Stereoselective total synthesis of (+)-artemisinin

✍ Scribed by J.S Yadav; R Satheesh Babu; G Sabitha

Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 163 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)02500-5

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✦ Synopsis

The total synthesis of the novel antimalarial drug, a sesquiterpene endoperoxide, (+)-artemisinin is described. The approach is flexible and stereoselective. The use of an intermolecular radical reaction on an intermediate iodolactone and a Wittig reaction on a ketone were employed for the synthesis.

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