The Effect of Sulfoxides on the Stereose
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Dr. Gloria HernΓ‘ndez-Torres; Prof.β
Dr. M. Carmen CarreΓ±o; Dr. Antonio Urbano; Pr
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Article
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2010
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John Wiley and Sons
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English
β 409 KB
π 1 views
## Abstract Good to excellent stereoselectivities were achieved in the reductive cyclization (with Et~3~SiH/trimethylsilyl trifluoromethanesulfonate (TMSOTf)) of enantiopure hydroxy sulfinyl ketones en route to 2,5β__cis__βdisubstituted tetrahydrofuran skeletons. Electrostatic effects of the exocyc