Stereoselective Synthesis of β-Amino-α-hydroxy(allyl)phosphinates and an Application to the Synthesis of a Building Block for Phosphinyl Peptides.
✍ Scribed by Takehiro Yamagishi; Takanori Kusano; Tsutomu Yokomatsu; Shiroshi Shibuya
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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37 8C) and the mixture was filtered in a UltraFree MC 30 000 MWCO centrifugal filtration unit (Millipore) at 3500 g for 7 min at 37 8C. The concentration of free substrate in the filtrate was quantified by ICP-MS and the bound fraction was calculated as % bound ([total]-[free])/[total]. The proton T
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